Mechanistic Insights into Ni-Catalyzed Difunctionalization of Alkenes Using Organoboronic Acids and Organic Halides: Understanding Remarkable Substrate-Dependent Regioselectivity
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DOI: 10.1021/acs.organomet.0c00043
Abstract: Transition metal catalyzed difunctionalization reactions of alkenes using simple chemical feedstocks are powerful strategies for the synthesis of valuable compounds and materials. Density functiona... read more here.
Keywords: insights catalyzed; catalyzed difunctionalization; alkenes using; mechanistic insights ... See more keywords
Mechanistic Insights into La-Catalyzed Amidation of Aldehyde with Amine.
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DOI: 10.1021/acs.orglett.9b04445
Abstract: A new mechanism of La-catalyzed amidation of N-methylbenzylamine with p-chlorobenzaldehyde has been computationally proposed, where L2La[NR1R2] (I) rather than previously proposed L2La[OCHRNR1R2] (II) is the catalytically active species. Interestingly, the side-product alcohol acting as a… read more here.
Keywords: amidation aldehyde; catalyzed amidation; insights catalyzed; aldehyde amine ... See more keywords