Fundamental Insights into the Reactivity and Utilization of Open Metal Sites in Cu(I)-MFU-4l
Sign Up to like & getrecommendations! Published in 2019 at "Organometallics"
DOI: 10.1021/acs.organomet.9b00351
Abstract: Metal–organic frameworks (MOFs) having open metal sites have the potential to approach the activity of homogeneous organometallic complexes, thus combining the advantages of homogeneous and heterogeneous catalysis. We present a fundamental study of the effectiveness… read more here.
Keywords: metal; sites mfu; open metal; insights reactivity ... See more keywords
Experimental, Spectroscopic, and Computational Insights into the Reactivity of “Methanal” with 2-Naphthylamines
Sign Up to like & getrecommendations! Published in 2023 at "Molecules"
DOI: 10.3390/molecules28041549
Abstract: The reactions of 2-naphthylamine and methyl 6-amino-2-naphthoate with formalin and paraformaldehyde were studied experimentally, spectrally, and by quantum chemical calculations. It was found that neither the corresponding aminals nor imines were formed under the described… read more here.
Keywords: insights reactivity; methanal naphthylamines; reactivity methanal; experimental spectroscopic ... See more keywords
New Insights into the Reactivity of Detonation Nanodiamonds during the First Stages of Graphitization
Sign Up to like & getrecommendations! Published in 2021 at "Nanomaterials"
DOI: 10.3390/nano11102671
Abstract: The present study aims to compare the early stages of graphitization of the same DND source for two annealing atmospheres (primary vacuum, argon at atmospheric pressure) in an identical set-up. DND samples are finely characterized… read more here.
Keywords: graphitization; insights reactivity; stages graphitization; detonation nanodiamonds ... See more keywords