Articles with "insights reductive" as a keyword



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Mechanistic insights into reductive deamination with hydrosilanes catalyzed by B(C6F5)3: A DFT study

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Published in 2022 at "Frontiers in Chemistry"

DOI: 10.3389/fchem.2022.1025135

Abstract: Selective defunctionalization of synthetic intermediates is a valuable approach in organic synthesis. Here, we present a theoretical study on the recently developed B(C6F5)3/hydrosilane-mediated reductive deamination reaction of primary amines. Our computational results provide important insights… read more here.

Keywords: reductive deamination; insights reductive; deamination; c6f5 ... See more keywords