Metallophilic interactions: observations of the shortest metallophilicinteractions between closed shell (d10d10, d10d8, d8d8) metal ions [MM' M = Hg(ii) and Pd(ii) and M' = Cu(i), Ag(i), Au(i), and Pd(ii)].
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DOI: 10.1039/d0dt01008a
Abstract: The salt metathesis reaction of two equivalents of 8-lithioquinoline (C6H6NLi) with HgBr2 afforded bis(quinoline-8-yl)mercury, [(C6H6N)2Hg]. Bis(quinoline-8-yl)mercury has been used for the synthesis of a series of heteronuclear complexes of the type [(C6H6N)2M·M']·X-n [M = Hg;… read more here.
Keywords: metallophilic interactions; interactions observations; analysis; metal ions ... See more keywords