Controlled interconversion of macrocyclic atropisomers via defined intermediates
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DOI: 10.1038/s41467-024-50739-6
Abstract: Macrocyclic conformations play a crucial role in regulating their properties. Our understanding of the determinants to control macrocyclic conformation interconversion is still in its infancy. Here we present a macrocycle, octamethyl cyclo[4](1,3-(4,6)-dimethylbenzene)[4]((4,6-benzene)(1,3-dicarboxylate) (OC-4), that can… read more here.
Keywords: c2v c4v; interconversion; controlled interconversion; interconversion macrocyclic ... See more keywords