Robust Interfacial Hydrogen-Bond Network on Positively Charged Ru-N-Ni Dual Sites Boosts Alkaline Hydrogen Electrocatalysis.
Sign Up to like & getrecommendations! Published in 2025 at "Advanced materials"
DOI: 10.1002/adma.202512568
Abstract: Ruthenium (Ru)-based dual-site catalysts can efficiently accelerate alkaline hydrogen electrocatalytic kinetics by virtue of the well-balanced competitive adsorptions of multiple reaction intermediates. However, their insufficient mass transfer makes them far away from the applications, largely… read more here.
Keywords: hydrogen bond; hydrogen; interfacial hydrogen; bond network ... See more keywords
Exploring the Interfacial Hydrogen Transfer between Pt and the Siliceous Framework and Its Promotional Effect on the Isotope Catalytic Exchange.
Sign Up to like & getrecommendations! Published in 2024 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.4c03725
Abstract: Interfacial hydrogen transfer between metal particles and catalyst supports is a ubiquitous phenomenon in heterogeneous catalysis, and this occurrence on reducible supports has been established, yet controversies remain about how hydrogen transfer can take place… read more here.
Keywords: hydrogen transfer; effect; interfacial hydrogen; hydrogen ... See more keywords
Interfacial Hydrogen-Bonding Network and Active-Site Electronic Structure Modulation via Indium Doping in RuO2 for Efficient and Durable OER.
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DOI: 10.1021/acsami.5c15561
Abstract: The challenged stability of iridium-free metal oxides in proton exchange membrane (PEM) water electrolyzers has always posed challenges that hinder the development of hydrogen energy production by water splitting. To overcome this challenge, we strategically… read more here.
Keywords: indium; interfacial hydrogen; bonding network; hydrogen bonding ... See more keywords
Interfacial Hydrogen-Bond Network Regulation Tuned Water Dissociation Enables Selective Chlorination of Alkenes.
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DOI: 10.1021/jacs.5c00818
Abstract: Electrocatalytically selective chlorination of olefins in Cl--containing solutions is a sustainable method for synthesizing chlorohydrin/vicinal dichloride; however, controlling the selectivity is challenging. Here, aqueous/dimethyl carbonate (DMC) hybrid electrolytes with different H2O/DMC ratios are designed to… read more here.
Keywords: chlorination; hydrogen bond; interfacial hydrogen; selective chlorination ... See more keywords
Immobilized Azole Layer Tunes Interfacial Hydrogen Source for CO2 Electroreduction in Strong Acid.
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DOI: 10.1021/jacs.5c11829
Abstract: Achieving selective electrochemical CO2 reduction reaction (CO2RR) in strong acid holds potential to resolve the "carbonate formation" problem yet is hindered by the competing hydrogen evolution reaction (HER). The interplay between different hydrogen sources (i.e.,… read more here.
Keywords: layer; hydrogen source; interfacial hydrogen; strong acid ... See more keywords