Enantioselective Intermolecular C-O Bond Formation in the Desymmetrization of Diarylmethines Employing a Guanidinylated Peptide-Based Catalyst.
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DOI: 10.1021/jacs.7b11197
Abstract: We report a series of enantioselective C-O bond cross-coupling reactions based on remote symmetry breaking processes in diarylmethine substrates. The key to the chemistry is multifunctional guanidinylated peptide-based ligands that allow highly selective, intermolecular Cu-catalyzed… read more here.
Keywords: peptide based; enantioselective intermolecular; intermolecular bond; guanidinylated peptide ... See more keywords
Nature and role of the weak intermolecular bond in enantiomeric conformations of H2O2–noble gas adducts: a chiral prototypical model
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DOI: 10.1039/d0nj06135b
Abstract: The role and nature of the weak intermolecular bond in the H2O2–noble gas enantiomeric conformations are presented. Charge transfer associated with the formation of a weak intermolecular hydrogen bond tends to stabilize the cis-barrier conformation. read more here.
Keywords: weak intermolecular; noble gas; enantiomeric conformations; h2o2 noble ... See more keywords