Copper-Catalyzed Intermolecular Carboamination of Alkenes Induced by Visible Light.
Sign Up to like & getrecommendations! Published in 2019 at "Organic letters"
DOI: 10.1021/acs.orglett.9b00252
Abstract: A photoinduced copper-catalyzed three-component reaction involving carbohalide, alkene and amine has been developed, leading to valuable fluoroalkyl-containing amines. A sole inexpensive CuCl is used as the photo- and coupling catalyst. A broad array of substrates… read more here.
Keywords: catalyzed intermolecular; induced visible; intermolecular carboamination; carboamination alkenes ... See more keywords
Catalytic Intermolecular Carboamination of Unactivated Alkenes via Directed Aminopalladation.
Sign Up to like & getrecommendations! Published in 2017 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.7b06520
Abstract: An intermolecular 1,2-carboamination of unactivated alkenes proceeding via a Pd(II)/Pd(IV) catalytic cycle has been developed. To realize this transformation, a cleavable bidentate directing group is used to control the regioselectivity of aminopalladation and stabilize the… read more here.
Keywords: carboamination unactivated; aminopalladation; intermolecular carboamination; reaction ... See more keywords
Intermolecular Carboamination of Unactivated Alkenes.
Sign Up to like & getrecommendations! Published in 2018 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.8b07023
Abstract: Herein, we report the first example of group transfer radical addition of O-vinylhydroxylamine derivatives onto unactivated alkenes. By utilizing O-vinylhydroxylamine derivatives as both the N- and C-donors, this reaction enables intermolecular carboamination of unactivated alkenes… read more here.
Keywords: carboamination; carboamination unactivated; intermolecular carboamination; unactivated alkenes ... See more keywords