Intermolecular N–N Coupling of a Dinitrosyl Iron Complex Induced by Hydrogen Bond Donors in the Secondary Coordination Sphere
Sign Up to like & getrecommendations! Published in 2025 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.4c12787
Abstract: The intermolecular N–N coupling of NO in a dinitrosyl iron complex (DNIC) induced by hydrogen bond donors in the secondary coordination sphere to form N2O is reported. A family of complexes containing pendant anilines in… read more here.
Keywords: coupling dinitrosyl; secondary coordination; coordination sphere; intermolecular coupling ... See more keywords
Nitrene-mediated intermolecular N–N coupling for efficient synthesis of hydrazides
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DOI: 10.1038/s41557-021-00650-0
Abstract: N–N linkages are found in many natural compounds and endow fascinating structural and functional properties. In comparison to the myriad methods for the construction of C–N bonds, chemistry for N–N coupling, especially in an intermolecular… read more here.
Keywords: nitrene mediated; synthesis hydrazides; chemistry; intermolecular coupling ... See more keywords