Copper-Catalyzed Enantioselective Intra- and Intermolecular Desymmetrization of Azetidiniums by Carbon Nucleophiles.
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DOI: 10.1021/jacs.5c17131
Abstract: Disclosed here is a transition-metal-catalyzed enantioselective ring-opening of azetidiniums. It also represents the first demonstration of catalytic enantioselective intramolecular desymmetrization of prochiral azetidiniums. With a cheap copper salt as the catalyst and a commercially available… read more here.
Keywords: intermolecular desymmetrization; desymmetrization; catalyzed enantioselective; enantioselective intra ... See more keywords