Photoredox-Catalyzed Intermolecular Remote C-H and C-C Vinylation via Iminyl Radicals.
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DOI: 10.1021/acs.orglett.8b02540
Abstract: A unified strategy for intermolecular remote C(sp3)-H and C-C vinylation of O-acyl oximes with vinyl boronic acids has been achieved. This strategy is enabled by photoreductive generation of iminyl radicals from O-acyl oximes under irradiation… read more here.
Keywords: vinylation; catalyzed intermolecular; remote vinylation; iminyl radicals ... See more keywords