Adducts of Donor-Functionalized Ar3P with the Soft Lewis Acid I2: Probing Simultaneous Lewis Acidity and Basicity at Internally Solvated P(III) Centers.
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DOI: 10.1021/acs.inorgchem.7b00278
Abstract: The enhancement of donor strength of ortho-functionalized triarylphosphanes is shown to occur via different mechanisms for O- and N-donor substituents, with internal solvation of the phosphorus center observed for N donors. Nevertheless, the steric congestion… read more here.
Keywords: donor; donor functionalized; lewis acid; internal solvation ... See more keywords