Dioxygen Activation by Internally Aromatic Metallacycle: Crystallographic Structure and Mechanistic Investigations
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DOI: 10.1016/j.isci.2020.101379
Abstract: Summary Mononuclear metal-peroxo species are invoked as the key intermediates in metalloenzymatic or synthetic catalysis. However, either transience or sluggishness reactivity of synthetic analogs of metal-peroxo species impedes our understanding of oxygen activation mechanism. Herein,… read more here.
Keywords: osmium; peroxo; aromatic metallacycle; internally aromatic ... See more keywords