Topology Conversions of Non-Interpenetrated Metal–Organic Frameworks to Doubly Interpenetrated Metal–Organic Frameworks
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DOI: 10.1021/acs.chemmater.6b05277
Abstract: Non-interpenetrated three-dimensional (3D) metal–organic frameworks (MOFs) with both an interpenetration-favorable (3,5)-c hms topology and an interpenetration-unfavorable (3,5)-c gra topology are converted to doubly interpenetrated analogues with hms-c topology by thermal treatment, even in the absence… read more here.
Keywords: interpenetrated metal; metal organic; doubly interpenetrated; topology ... See more keywords
A five-fold interpenetrated metal-organic framework showing a large variation in thermal expansion behaviour owing to dramatic structural transformation upon dehydration-rehydration.
Sign Up to like & getrecommendations! Published in 2017 at "Chemical communications"
DOI: 10.1039/c6cc07995d
Abstract: A five-fold interpenetrated metal organic framework (MOF) has been shown to exhibit anomalous thermal expansion due to the combined effect of hinge-like motion and sliding of individual diamondoid networks. Upon dehydration, the MOF undergoes dramatic… read more here.
Keywords: interpenetrated metal; expansion; metal organic; five fold ... See more keywords