Co-ligand tuned pyrimidine-2-carboxylate Mn(ii) complexes from a 2D 63 layer to an interpenetrated srs-net.
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DOI: 10.1039/c7dt01045a
Abstract: A 63 2D layer complex [Mn3Cl3(L3)]n·H2O (1) (L = pyrimidine-2-carboxylate) was obtained by assembling 2-cyanopyrimidine and manganese chloride, in which the L ligands were generated in situ. In 1 six-membered Mn rings were constructed from… read more here.
Keywords: interpenetrated srs; chloride anions; pyrimidine carboxylate; srs net ... See more keywords