From 2D → 3D interpenetration to packing: N coligand-driven structural assembly and tuning of luminescent sensing activities towards Fe3+ and Cr2O72- ions.
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DOI: 10.1039/c8dt00909k
Abstract: Three new luminescent transition coordination polymers, namely, {[Cd(L)(4,4-bpy)]·DMF·H2O}n (1), {[Cd2(L)2(bpe)2]·3DMF·2.5H2O}n (2), and {[Cd(L)(bibp)]·2DMF}n (3), (H2L = 4,4'-[benzene-1,3-diylbis(methanediylsulfanediyl)]dibenzoic acid, 4,4-bpy = 4,4-bipyridine, bpe = 1,2-bis(4-pyridyl)ethylene, and bibp = 4,4'-bis(benzoimidazo-1-ly)biphenyl), were solvothermally synthesized using Cd2+ ions and… read more here.
Keywords: cr2o72 ions; towards fe3; interpenetration packing; fe3 cr2o72 ... See more keywords