Diastereoselective construction of bridged piperidines through an interrupted dearomative reduction.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc02225g
Abstract: An interrupted dearomative reduction strategy was developed to transform planar chalcone-based pyridinium salts into structurally intriguing bridged piperidines in a completely regio- and diastereoselective manner. This reaction proceeded successfully by using cheap and easily accessible… read more here.
Keywords: diastereoselective construction; interrupted dearomative; construction bridged; dearomative reduction ... See more keywords
Solvent-controlled halohydroxylation or C3-C2 coupling of pyridinium salts through an interrupted dearomative reduction.
Sign Up to like & getrecommendations! Published in 2024 at "Chemical communications"
DOI: 10.1039/d3cc05212e
Abstract: Herein, we report an efficient and easily operable method to halohydroxylate pyridiniums through an interrupted dearomative reduction strategy. In this process, we make the most of the halide anion from the pyridinium salts by performing… read more here.
Keywords: interrupted dearomative; pyridinium salts; solvent controlled; dearomative reduction ... See more keywords