Direct Determination of the Rate of Intersystem Crossing in a Near-IR Luminescent Cr(III) Triazolyl Complex.
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.3c01543
Abstract: A detailed understanding of the dynamics of photoinduced processes occurring in the electronic excited state is essential in informing the rational design of photoactive transition-metal complexes. Here, the rate of intersystem crossing in a Cr(III)-centered… read more here.
Keywords: intersystem; spectroscopy; rate intersystem; luminescent iii ... See more keywords
Abnormal Reverse Intersystem Crossing of Polaron-Pair States and Its Conversion to Intersystem Crossing via the Regulation of Intermolecular Electron-Hole Spacing Distance
Sign Up to like & getrecommendations! Published in 2020 at "Physical review applied"
DOI: 10.1103/physrevapplied.14.024011
Abstract: Reverse intersystem crossing (RISC) unexpectedly dominates the interconversion of polaron pairs in the traditional fluorescent material 4-(dicyanomethylene)-2-tert-butyl-6-(1,1,7,7-tetramethyljulolidin-4-yl-vinyl)-4H-pyran (DCJTB), with a large energy gap (\ensuremath{\Delta}${E}_{\mathrm{ST}}$) between singlet and triplet excitons, by employing the magnetoelectroluminescence detection technique.… read more here.
Keywords: pair; polaron; intersystem crossing; intersystem ... See more keywords