Total Synthesis of a PPAP, Nemorosonol, Using a Tandem Michael Addition-Intramolecular Aldol Reaction.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c01745
Abstract: A strategy for constructing a tricyclo[4.3.1.03,7]decane skeleton, which is common to many polycyclic polyprenylated acylphloroglucinols, has been established. The key step was a tandem Michael addition-intramolecular aldol reaction with 3-ethoxy-1-phenyl-2-proyn-1-one, which affords a tricyclo[4.3.1.03,7]decane skeleton… read more here.
Keywords: addition intramolecular; michael addition; aldol reaction; intramolecular aldol ... See more keywords
Total syntheses of (±)-penicibilaenes A and B via intramolecular aldol condensation
Sign Up to like & getrecommendations! Published in 2021 at "Organic Chemistry Frontiers"
DOI: 10.1039/d1qo01251g
Abstract: Concise total syntheses of penicibilaenes A and B were achieved via intramolecular aldol condensation and other key reactions. read more here.
Keywords: total syntheses; via intramolecular; aldol condensation; intramolecular aldol ... See more keywords