Copper-catalyzed Enantioselective Intramolecular Alkylboron Allylic Alkylation
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DOI: 10.1246/cl.180147
Abstract: A reductive C–C-bond-forming cyclization of vinyl-terminated allyl chlorides via alkene hydroboration with 9-BBN-H followed by Cu-catalyzed asymmetric intramolecular allylic alkylation with a new chiral phosphoramidite ligand produced six-membered ring compounds with a tertiary or quaternary… read more here.
Keywords: intramolecular alkylboron; allylic alkylation; enantioselective intramolecular; catalyzed enantioselective ... See more keywords