Visible-Light-Promoted Intramolecular α-Allylation of Aldehydes in the Absence of Sacrificial Hydrogen Acceptors.
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DOI: 10.1021/acs.orglett.0c02742
Abstract: We report herein an unprecedented protocol for radical cyclization of aldehydes with pendant alkenes via synergistic photoredox, cobaloxime, and amine catalysis. The transformation was achieved in the absence of external oxidants, providing a variety of… read more here.
Keywords: promoted intramolecular; aldehydes absence; intramolecular allylation; visible light ... See more keywords