CuOTf-mediated intramolecular diborene hydroarylation.
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DOI: 10.1039/c7cc07371b
Abstract: Upon complexation to CuOTf, a PMe3-stabilized bis(9-anthryl) diborene slowly undergoes an intramolecular hydroarylation reaction at room temperature. Subsequent triflation of the B-H bond with CuOTf, followed by a PMe3 transfer, finally yields a cyclic sp2-sp3… read more here.
Keywords: hydroarylation; cuotf mediated; intramolecular diborene; mediated intramolecular ... See more keywords