Reaction Site Designation by Intramolecular Electric Field in Tröger's‐Base‐Derived Conjugated Microporous Polymer for Near‐Unity Selectivity of CO2 Photoconversion
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DOI: 10.1002/adma.202210693
Abstract: To facilitate solar‐driven overall CO2 and H2O convsersion into fuels and O2, a series of covalent microporous polymers derived from Tröger's base are synthesized featuring flexural backbone and unusual charge‐transfer properties. The incorporation of rigid… read more here.
Keywords: reaction; ger base; co2; base ... See more keywords
Orbital Polarization-Dependent Fragment Twist-Induced Intramolecular Electric-Field-Driven Charge Transfer
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DOI: 10.3390/molecules28041801
Abstract: Defects, such as twisting, in fused aromatic hydrocarbons disrupt the plane of the π orbital. The twisted structure induces an electric field in the system and affects the spectra. In this work, theoretical studies show… read more here.
Keywords: electric field; charge transfer; field; intramolecular electric ... See more keywords