Intramolecular Electrostatic Effects on O2, CO2, and Acetate Binding to a Cationic Iron Porphyrin.
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DOI: 10.1021/acs.inorgchem.0c02703
Abstract: Noncovalent electrostatic interactions are important in many biological and chemical reactions, especially those that involve charged intermediates. There has been a growing interest in using electrostatic ligand designs-placing charges in the second coordination sphere-to improve… read more here.
Keywords: iron porphyrin; binding; electrostatic effects; intramolecular electrostatic ... See more keywords