Articles with "intramolecular heck" as a keyword



Photo by karsten116 from unsplash

Pd-Catalyzed Cascade Intramolecular Heck Cyclization/Dearomatization of Indoles for the Construction of Two All-Carbon Quaternary Centers.

Sign Up to like & get
recommendations!
Published in 2022 at "Organic letters"

DOI: 10.1021/acs.orglett.2c03691

Abstract: A facile Pd-catalyzed cascade of intramolecular Heck cyclization/alkylpalladium activated dearomatization of aryl alkyne-tethered indole is described. In this single step two nonadjacent all-carbon quaternary centers, two nitrogen-containing heterocycles, and three C(sp2)-C(sp3) bonds are efficiently furnished.… read more here.

Keywords: intramolecular heck; catalyzed cascade; cascade intramolecular; carbon quaternary ... See more keywords