Intramolecular Magnetic Interaction in a Photogenerated Dual Angular Momentum System in a Terbium-Phthalocyaninato 1:1 Complex.
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.0c03524
Abstract: Intramolecular magnetic interaction between a localized open-shell 4f-electronic system and a photoexcited macrocyclic π-conjugate system in terbium-phthalocyaninnato (Tb-Pc) 1:1 complex was investigated using variable-temperature variable-field magnetic circular dichroism (VTVH MCD) spectroscopy. The 1:1 complex [Tb(Pc)(cyclen)]Cl… read more here.
Keywords: system; magnetic interaction; angular momentum; interaction ... See more keywords
Assessment of the intramolecular magnetic interactions in the highly saddled iron(iii) porphyrin π-radical cations: the change from planar to saddle conformations.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c9dt02714a
Abstract: The intramolecular magnetic interactions in one-electron oxidized iron(iii) porphyrin π-radical cations, [Fe(OETPP˙)Cl][SbCl6] (1), [Fe(OMTPP˙)Cl][SbCl6] (2) and [Fe(TPP˙)Cl][SbCl6] (3), have been compared by means of X-ray crystallography, SQUID magnetometry, cyclic voltammetry, UV-Vis spectroelectrochemical analysis, NMR spectroscopy… read more here.
Keywords: porphyrin radical; iii porphyrin; iron; intramolecular magnetic ... See more keywords