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Published in 2019 at "Organometallics"
DOI: 10.1021/acs.organomet.9b00498
Abstract: We report the synthesis of unsaturated silacycles via an intramolecular silyl-Heck reaction. Using palladium catalysis, silicon electrophiles tethered to alkenes cyclize to form 5- and 6-membered silicon heterocycles. The effects of alkene substitution and tether…
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Keywords:
silyl heck;
silyl;
via intramolecular;
synthesis unsaturated ... See more keywords