Stereoselective Synthesis of Fused Vinylcyclopropanes by Intramolecular Tsuji–Trost Cascade Cyclization
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DOI: 10.1021/acs.orglett.8b02232
Abstract: A stereoselective intramolecular Tsuji–Trost cascade cyclization of (homo)allylic vicinal diacetates with a pendant β-ketoamide or related carbon nucleophile to give γ-lactam-fused vinylcyclopropanes is reported. In addition to two new rings, the products contain three new… read more here.
Keywords: cascade cyclization; fused vinylcyclopropanes; tsuji trost; trost cascade ... See more keywords