Role of electron in intramolecular vibrational energy redistribution: a simulation of time- and frequency-resolved CARS spectrum
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DOI: 10.1039/c9ra04645c
Abstract: The electron plays a mediator role in the IVR process and significantly increases the vibrational energy transfer efficiency. read more here.
Keywords: role; vibrational energy; intramolecular vibrational; role electron ... See more keywords
Antenna-coupled infrared nanospectroscopy of intramolecular vibrational interaction.
Sign Up to like & getrecommendations! Published in 2023 at "Proceedings of the National Academy of Sciences of the United States of America"
DOI: 10.1073/pnas.2220852120
Abstract: Many photonic and electronic molecular properties, as well as chemical and biochemical reactivities are controlled by fast intramolecular vibrational energy redistribution (IVR). This fundamental ultrafast process limits coherence time in applications from photochemistry to single… read more here.
Keywords: nanospectroscopy; spectroscopy; vibrational interaction; intramolecular vibrational ... See more keywords
Cavity-enabled enhancement of ultrafast intramolecular vibrational redistribution over pseudorotation
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DOI: 10.1126/science.add0276
Abstract: Vibrational strong coupling (VSC) between molecular vibrations and microcavity photons yields a few polaritons (light-matter modes) and many dark modes (with negligible photonic character). Although VSC is reported to alter thermally activated chemical reactions, its… read more here.
Keywords: cavity; spectroscopy; chemistry; vsc ... See more keywords