Insight into the Selective Conversion via a Steered Adsorption and Protonation from Tantalates‐based Solid Acid's Intrinsic Proton for Hydride‐transfer Reduction
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DOI: 10.1002/cctc.202000453
Abstract: Brønsted solid acids have popularly been used as catalysts or supports for many hydrogenation reactions, while it is uncertain if their structural H species could significantly enhance velocity and reusability for these reactions. In this… read more here.
Keywords: solid acid; selective conversion; intrinsic proton; insight selective ... See more keywords
Asymmetric Hydrophosphonylation of Imines to Construct Highly Stable Covalent Organic Frameworks with Efficient Intrinsic Proton Conductivity.
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DOI: 10.1021/jacs.2c00429
Abstract: Imine-linked covalent organic frameworks (COFs) have received widespread attention because of their structure features such as high crystallinity and tunable pores. However, the intrinsic reversibility of the imine bond leads to the poor stability of… read more here.
Keywords: proton conductivity; organic frameworks; hydrophosphonylation; asymmetric hydrophosphonylation ... See more keywords