On the calculation of the inverse isotope effect in PdH(D): A Migdal-Eliashberg theory approach
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Physics and Chemistry of Solids"
DOI: 10.1016/j.jpcs.2018.03.025
Abstract: Abstract Replacement of hydrogen by deuterium in palladium hydride results in higher superconducting temperatures and in an anomalous isotope effect that has not been yet fully explained. In this work, we try a new approach… read more here.
Keywords: pdh; effect; inverse isotope; isotope effect ... See more keywords
Inverse Isotope Effects in Single-Crystal to Single-Crystal Reactivity and the Isolation of a Rhodium Cyclooctane σ-Alkane Complex
Sign Up to like & getrecommendations! Published in 2022 at "Organometallics"
DOI: 10.1021/acs.organomet.1c00639
Abstract: The sequential solid/gas single-crystal to single-crystal reaction of [Rh(Cy2P(CH2)3PCy2)(COD)][BArF4] (COD = cyclooctadiene) with H2 or D2 was followed in situ by solid-state 31P{1H} NMR spectroscopy (SSNMR) and ex situ by solution quenching and GC-MS. This… read more here.
Keywords: single crystal; crystal single; inverse isotope; alkane complex ... See more keywords