On the Mechanism of the Inverse Vulcanization of Elemental Sulfur: Structural Characterization of Poly(sulfur-random-(1,3-diisopropenylbenzene)).
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.3c03604
Abstract: Organosulfur polymers, such as those derived from elemental sulfur, are an important new class of macromolecules that have recently emerged via the inverse vulcanization process. Since the launching of this new field in 2013, the… read more here.
Keywords: vulcanization; inverse vulcanization; poly dib; mechanism ... See more keywords
Scalable High Refractive Index polystyrene-sulfur nanocomposites via in situ inverse vulcanization
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DOI: 10.1038/s41598-020-71227-z
Abstract: In this work, we demostrate the preparation of low cost High Refractive Index polystyrene-sulfur nanocomposites in one step by combining inverse vulcanization and melt extrusion method. Poly(sulfur-1,3-diisopropenylbenzene) (PS-SD) copolymer nanoparticles (5 to 10 wt%) were… read more here.
Keywords: inverse vulcanization; high refractive; polystyrene; sulfur ... See more keywords
High strength, epoxy cross-linked high sulfur content polymers from one-step reactive compatibilization inverse vulcanization
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DOI: 10.1039/d1sc05896g
Abstract: Inverse vulcanization provides a simple, solvent-free method for the preparation of high sulfur content polymers using elemental sulfur, a byproduct of refining processes, as feedstock. Despite the successful demonstration of sulfur polymers from inverse vulcanization… read more here.
Keywords: high sulfur; inverse vulcanization; content polymers; sulfur ... See more keywords
Inverse Vulcanization of Elemental Sulfur Catalyzed by Trialkyl Amines
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DOI: 10.1039/d3gc01102j
Abstract: In this study, catalytic inverse vulcanization based on trialkyl amines (TAAs) is presented. With oleophilic alkyl chain moieties, low-cost organic TAAs promote time-efficient reactions as nucleophilic activators, even at a... read more here.
Keywords: inverse vulcanization; trialkyl amines; vulcanization elemental; sulfur catalyzed ... See more keywords