Charge-Inverted Hydrogen-Bridged Bond in HCa(μ-H)3E (E = Si, Ge, and Sn): Matrix Isolation Infrared Spectroscopic and Theoretical Studies.
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DOI: 10.1021/acs.inorgchem.0c02132
Abstract: Matrix isolation infrared spectroscopy combined with quantum-chemical calculations were employed to study the reactions of calcium atoms with silane, germane, and stannane in a 4 K argon matrix. The ion pairs [HCa]+ and [EH3]- (E… read more here.
Keywords: matrix isolation; inverted hydrogen; hca; charge inverted ... See more keywords