Synthetic and Spectroscopic Investigations Enabled by Modular Synthesis of Molecular Phosphaalkyne Precursors.
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DOI: 10.1021/jacs.8b09845
Abstract: A series of dibenzo-7-phosphanorbornadiene compounds, Ph3PC(R)PA (1-R; A = C14H10, anthracene; R = Me, Et, iPr, sBu), are reported to be capable of thermal fragmentation to generate alkyl-substituted phosphaalkynes (RC≡P) concomitant with triphenylphosphine and anthracene.… read more here.
Keywords: investigations enabled; modular synthesis; synthetic spectroscopic; spectroscopic investigations ... See more keywords