Mechanistic Investigations of Reactions of the Frustrated Lewis Pairs (Triarylphosphines/B(C6F5)3) with Michael Acceptors.
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DOI: 10.1021/acs.orglett.6b03868
Abstract: Frustrated Lewis pair (FLP)-catalyzed reduction of Michael acceptors is a challenging reaction that proceeds with specific FLP structures. Kinetics and equilibrium of the reactions of two phosphines (Ar3P), namely tri(1-naphthyl)phosphine and tri(o-tolyl)phosphine, are reported with… read more here.
Keywords: lewis pairs; investigations reactions; mechanistic investigations; reactions frustrated ... See more keywords