Computationally rational design of metal‐involving halogen bonds with π‐covalency: Structures and bonding analysis
Sign Up to like & getrecommendations! Published in 2022 at "Journal of Computational Chemistry"
DOI: 10.1002/jcc.27036
Abstract: Traditional π‐covalent interactions have been proved in the non‐metal halogen bond adducts formed by chloride and halogenated triphenylamine‐based radical cations. In this study, we have rationally designed two metal‐involving halogen bond adducts with π‐covalency property,… read more here.
Keywords: halogen; involving halogen; halogen bond; metal ... See more keywords
Exploring Au(i) involving halogen bonding with N-heterocyclic carbene Au(i) aryl complexes in crystalline media
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DOI: 10.1039/d3sc00373f
Abstract: Among the known types of non-covalent interactions with a Au(i) metal center, Au(i) involving halogen bonding (XB) remains a rare phenomenon that has not been studied systematically. Herein, using five N-heterocyclic carbene (NHC) Au(i) aryl… read more here.
Keywords: heterocyclic carbene; involving halogen; aryl complexes; halogen bonding ... See more keywords