Direct synthesis of 5-methylfurfural from D-fructose by iodide-mediated transfer hydrogenation.
Sign Up to like & getrecommendations! Published in 2021 at "ChemSusChem"
DOI: 10.1002/cssc.202102021
Abstract: Herein, we firstly report a robust catalytic system for the green synthesis of 5-methylfurfural (5-MF) by iodide-mediated transfer hydrogenation. Around 50% of 5-MF was yielded from D-fructose within 7.5 min using NaI as the catalyst… read more here.
Keywords: mediated transfer; transfer hydrogenation; iodide mediated; synthesis methylfurfural ... See more keywords
Switching of Regioselectivity in a Perfluorohexyl Iodide Mediated Synthesis of Phenylimidazo[1,2‐a]pyridines
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DOI: 10.1002/ejoc.201601586
Abstract: An array of 3-phenylimidazo[1,2-a]pyridines has been synthesized via perfluorohexyl iodide-mediated coupling of 2-aminopyridines and phenylacetylenes. In-situ iodination of the terminal alkyne by perfluorohexyl iodide reverses the polarity by generating a transient electrophilic iodoalkyne, altering the… read more here.
Keywords: perfluorohexyl; phenylimidazo pyridines; regioselectivity; iodide mediated ... See more keywords
Ammonium iodide-mediated electrosynthesis of unsymmetrical thiosulfonates from arenesulfonohydrazides and thiols
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DOI: 10.1016/j.mencom.2019.01.027
Abstract: Unsymmetrical thiosulfonates were synthesized from thiols and arenesulfonohydrazides by their electrolysis in undivided cell equipped with graphite anode and stainless steel cathode under high current density applying NH4I both as a redox catalyst and a… read more here.
Keywords: iodide mediated; thiosulfonates arenesulfonohydrazides; ammonium iodide; electrosynthesis unsymmetrical ... See more keywords