Room-Temperature Copper-Mediated Radiocyanation of Aryldiazonium Salts and Aryl Iodides via Aryl Radical Intermediates.
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DOI: 10.1021/jacs.3c00422
Abstract: Radiocyanation is an attractive strategy for incorporating carbon-11 into radiotracer targets, particularly given the broad scope of acyl moieties accessible from nitriles. Most existing methods for aromatic radiocyanation require elevated temperatures (Cu-mediated reactions of aryl… read more here.
Keywords: aryl iodides; radiocyanation; iodides via; aryl radical ... See more keywords