Crossbreeding Effect of Chalcogenation and Iodination on Benzene Additives Enables Optimized Morphology and 19.68% Efficiency of Organic Solar Cells
Sign Up to like & getrecommendations! Published in 2024 at "Advanced Science"
DOI: 10.1002/advs.202401405
Abstract: Volatile solid additives have attracted increasing attention in optimizing the morphology and improving the performance of currently dominated non‐fullerene acceptor‐based organic solar cells (OSCs). However, the underlying principles governing the rational design of volatile solid… read more here.
Keywords: chalcogenation iodination; effect chalcogenation; morphology; iodination ... See more keywords
Palladium-catalyzed meta-C H bond iodination of arenes with I2
Sign Up to like & getrecommendations! Published in 2020 at "Chinese Chemical Letters"
DOI: 10.1016/j.cclet.2019.09.057
Abstract: Abstract Palladium-catalyzed highly meta-selective C H iodination of phenylacetic acid, benzylphosphonate and benzylsulfonate scaffolds with molecular I2 is developed using a pyridine-type template. The practical ester linkages enable the directing template easily installed and readily… read more here.
Keywords: iodination; meta bond; palladium catalyzed; catalyzed meta ... See more keywords
Abiotic formation of organoiodine compounds by manganese dioxide induced iodination of dissolved organic matter.
Sign Up to like & getrecommendations! Published in 2018 at "Environmental pollution"
DOI: 10.1016/j.envpol.2018.02.001
Abstract: Iodination of dissolved organic matter (DOM) initiated by manganese oxide may represent an important source of organoiodine compounds (OICs) for iodide-containing waters. Here, Suwannee River natural organic matter was selected as model DOM, the OICs… read more here.
Keywords: iodination; iodination dissolved; formation; organic matter ... See more keywords
Iodination of terminal alkynes using KI/CuSO4 – A facile method with potential for radio-iodination
Sign Up to like & getrecommendations! Published in 2019 at "Tetrahedron Letters"
DOI: 10.1016/j.tetlet.2019.02.041
Abstract: Graphical abstract Herein, we report an efficient new method for iodination of terminal alkynes using stoichiometric KI and CuSO4 in acetate buffer that holds promise for further development into a method for radio-iodination. read more here.
Keywords: iodination; iodination terminal; terminal alkynes; method ... See more keywords
Selective C–H Iodination of (Hetero)arenes
Sign Up to like & getrecommendations! Published in 2021 at "Organic Letters"
DOI: 10.1021/acs.orglett.1c01530
Abstract: Iodoarenes are versatile intermediates and common synthetic targets in organic synthesis. Here, we present a strategy for selective C–H iodination of (hetero)arenes with a broad functional group tolerance. We demonstrate the utility and differentiation to… read more here.
Keywords: iodination; iodination hetero; hetero arenes; selective iodination ... See more keywords
Native Amino Group Directed Site-Selective ε-C(sp2)-H Iodination of Primary Amines.
Sign Up to like & getrecommendations! Published in 2023 at "Organic letters"
DOI: 10.1021/acs.orglett.2c04288
Abstract: Selective remote C-H activating amines using unmodified NH2 as a native directing group demonstrate compelling synthetic utilities. The 3-arylpropan-1-amine moiety is present in many drugs and candidates in clinical trials. Selective iodination of 3-arylpropan-1-amines on… read more here.
Keywords: native amino; sp2 iodination; selective sp2; group ... See more keywords
Denitrative Iodination of Nitroarenes via Light-Promoted Reduction.
Sign Up to like & getrecommendations! Published in 2025 at "Organic letters"
DOI: 10.1021/acs.orglett.5c01222
Abstract: Aryl iodides are essential synthons in organic synthesis, whose conventional preparations often suffer from poor selectivity or necessitate multistep procedures. Herein, we present a light-driven denitrative iodination as a one-step approach that directly converts nitroarenes… read more here.
Keywords: light promoted; via light; denitrative iodination; iodination nitroarenes ... See more keywords
Isodesmic C(sp2)-H Iodination of 2-Phenethylamines Directed by Native Primary Amino Groups.
Sign Up to like & getrecommendations! Published in 2025 at "Organic letters"
DOI: 10.1021/acs.orglett.5c02117
Abstract: The site-selective C-H functionalization of native phenethylamines remains a significant synthetic challenge due to the strong coordination ability of the primary amine group. Herein, a palladium-catalyzed isodesmic C(sp2)-H iodination of 2-phenethylamines directed by native, unprotected… read more here.
Keywords: phenethylamines directed; sp2 iodination; iodination phenethylamines; isodesmic sp2 ... See more keywords
In Situ Generation of Chiroptically-Active Gold-Peptide Superstructures Promoted by Iodination
Sign Up to like & getrecommendations! Published in 2019 at "ACS Nano"
DOI: 10.1021/acsnano.8b08805
Abstract: Peptide-mediated routes to the synthesis of plasmonic nanoparticles have been drawing increasing attention for the development of chiroptically active nanoscale architectures. However, designing a multifunctional peptide able to drive the formation of structurally defined nanomaterials… read more here.
Keywords: iodination; peptide; active gold; situ generation ... See more keywords
(E)-Di-iodination of Alkynes Using Dried Dowex H+/NaI Approach
Sign Up to like & getrecommendations! Published in 2019 at "ACS Omega"
DOI: 10.1021/acsomega.9b02577
Abstract: We investigated the usefulness of the dried Dowex H+/NaI approach for the selective di-iodination of alkynes. The Dowex H+/NaI approach selectively produces only (E)-di-iodinated products; it is very straightforward and nontoxic. The utilization of 2-propanol… read more here.
Keywords: iodination; dowex nai; dried dowex; approach ... See more keywords
Facile C–H iodination of electron deficient benzodithiophene-S,S-tetraoxide for the development of n-type polymers
Sign Up to like & getrecommendations! Published in 2020 at "Polymer Chemistry"
DOI: 10.1039/d0py01292k
Abstract: A C–H iodination reaction of the electron-poor building block, benzo[1,2-b:4,5-b0]-dithiophene-1,1,5,5-tetraoxide has been reported. This facile functionalization has led to the development of two novel n-type donor–acceptor conjugated polymers. read more here.
Keywords: iodination; iodination electron; facile iodination; type ... See more keywords