Multifunctional and Hierarchical Porous ZIF-8: Amine and Thiol Tagged via Mixed Multivariate Ligand Strategies for Enhanced CO2 and Iodine Adsorption.
Sign Up to like & getrecommendations! Published in 2024 at "ChemSusChem"
DOI: 10.1002/cssc.202401968
Abstract: This study demonstrated a simple and innovative way of using the direct de novo synthesis to fabricate the mesoporous structure and diverse functionality of ZIF-8 for environmental cleanup and gas storage applications. By introducing different… read more here.
Keywords: amine thiol; co2 iodine; adsorption; iodine adsorption ... See more keywords
From Supramolecular Organic Cages to Porous Covalent Organic Frameworks for Enhancing Iodine Adsorption Capability by Fully Exposed Nitrogen-Rich Sites.
Sign Up to like & getrecommendations! Published in 2023 at "Small"
DOI: 10.1002/smll.202301998
Abstract: In order to overcome the limitations of supramolecular organic cages for their incomplete accessibility of active sites in the solid state and uneasy recyclability in liquid solution, herein a nitrogen-rich organic cage is rationally linked… read more here.
Keywords: nitrogen rich; supramolecular organic; iodine adsorption; cage ... See more keywords
One-pot synthesis of nitrogen-rich aminal- and triazine-based hierarchical porous organic polymers with highly efficient iodine adsorption
Sign Up to like & getrecommendations! Published in 2020 at "Polymer"
DOI: 10.1016/j.polymer.2020.122401
Abstract: Abstract Design and preparation of porous adsorption materials for dealing with environmental issues is attractive and promising, but it remains some challenges such as effective capture of radioactive iodine. Here, two nitrogen-rich porous organic polymers… read more here.
Keywords: adsorption; organic polymers; nitrogen rich; porous organic ... See more keywords
Positional Isomerism: A Novel Paradigm for Enhancing Iodine Adsorption in Functionalized Metal-Organic Frameworks.
Sign Up to like & getrecommendations! Published in 2024 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.4c04012
Abstract: Porous metal-organic frameworks (MOFs) have shown great potential as adsorbents for capturing radioiodine, a major fission product generated during the reprocessing of nuclear fuel. However, studies exploring the correlation between the structure of MOFs and… read more here.
Keywords: spectroscopy; enhancing iodine; uio nh2; adsorption ... See more keywords
84-Nuclearity Lanthanide-Aluminum Cyclic Clusters: Promising Materials for Iodine Capture and Storage.
Sign Up to like & getrecommendations! Published in 2025 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.5c00684
Abstract: Developing high-performance adsorbents for iodine uptake and storage has become an urgent priority for safe disposal and long-term storage of nuclear waste. In this work, two cyclic lanthanide-aluminum clusters with the formula [Ln12Al72(hmp)60(C2H5O2)6(μ2-OH)120(μ3-OH)18(H2O)30]Cl24·(NO3)24·(H2O)x (Ln =… read more here.
Keywords: cyclic clusters; nuclearity lanthanide; iodine adsorption; storage ... See more keywords
Rapid iodine adsorption from vapor phase and solution by a nitrogen-rich covalent piperazine–triazine-based polymer
Sign Up to like & getrecommendations! Published in 2021 at "New Journal of Chemistry"
DOI: 10.1039/d1nj00122a
Abstract: The efficient capture of radioiodine from the waste of nuclear industries is a growing priority for the safe development of nuclear energy. However, because the iodine adsorption rate of previously reported adsorbents is very slow,… read more here.
Keywords: iodine; iodine adsorption; adsorption; nitrogen rich ... See more keywords
Fabrication of bimetallic MOF-74 derived materials for high-efficiency adsorption of iodine.
Sign Up to like & getrecommendations! Published in 2024 at "Dalton transactions"
DOI: 10.1039/d4dt01554a
Abstract: Owing to their high porosity, open metal sites, and huge surface area, metal-organic framework (MOF) materials are commonly employed in iodine adsorption processes. Bimetallic MOFs have drawn a lot of attention since mono-metal MOFs have… read more here.
Keywords: adsorption; mof materials; mof; iodine adsorption ... See more keywords
Spirobifluorene-BINOL-based microporous polymer nanoreactor for efficient 1H-tetrazole synthesis and iodine adsorption with facile charge transfer.
Sign Up to like & getrecommendations! Published in 2024 at "Nanoscale"
DOI: 10.1039/d4nr00599f
Abstract: Porous polymeric nanoreactors capable of multitasking are attractive and require a judicious design strategy. Herein, we describe an unusual approach for the synthesis of a porous polymer SBF-BINOL-6 by in situ formation of the BINOL… read more here.
Keywords: charge transfer; synthesis; polymer; iodine adsorption ... See more keywords
Constructing covalent organic frameworks with dense thiophene S sites for effective iodine capture
Sign Up to like & getrecommendations! Published in 2024 at "RSC Advances"
DOI: 10.1039/d4ra06333c
Abstract: Developing versatile sorption materials for radionuclides (e.g. iodine) capture has been a critical goal in nuclear energy and environmental science. At the same time, covalent organic frameworks (COFs), on account of their high porosity and… read more here.
Keywords: cof; tab cof; adsorption; iodine adsorption ... See more keywords
Iodine adsorption and electrochemical double-layer capacitor characteristics of activated carbon prepared from low-cost biomass
Sign Up to like & getrecommendations! Published in 2022 at "International Journal of Phytoremediation"
DOI: 10.1080/15226514.2022.2057420
Abstract: Abstract The efficient adsorption application and electric double-layer capacitor material with low-cost biomass-based activated carbon materials have been quite common recently. In this study, chestnut shell-based activated carbons were produced by chemical activation. ZnCl2, H3PO4,… read more here.
Keywords: adsorption; activated carbon; iodine adsorption; capacitor ... See more keywords
Nickel(II) Coordination Polymers Supported by Bis-pyridyl-bis-amide and Angular Dicarboxylate Ligands: Role of Ligand Flexibility in Iodine Adsorption
Sign Up to like & getrecommendations! Published in 2022 at "International Journal of Molecular Sciences"
DOI: 10.3390/ijms23073603
Abstract: Reactions of N‚N’-bis(3-pyridylmethyl)oxalamide (L1), N‚N’-bis(4-pyridylmethyl)oxalamide (L2), or N,N’-bis(3-pyridylmethyl)adipoamide) (L3) with angular dicarboxylic acids and Ni(II) salts under hydro(solvo)thermal conditions afforded a series of coordination polymers: {[Ni(L1)(OBA)(H2O)]·H2O}n (H2OBA = 4,4-oxydibenzoic acid), 1, {[Ni(L1)(SDA)(H2O)2]·H2O·CH3OH}n (H2SDA = 4,4-sulfonyldibenzoic… read more here.
Keywords: sda h2o; iodine adsorption; h2o; topology ... See more keywords