Crystalline Iodine Complexes of Amorphous Poly(vinyl acetate) as Studied by X-ray Diffraction, Vibrational Spectroscopy, and Computer Simulation
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DOI: 10.1021/acs.macromol.0c00612
Abstract: One of the typical amorphous polymers, atactic poly(vinyl acetate) (PVAc) has been found to form the two types of crystalline iodine complexes (α and β forms) with iodine ions when the sample is im... read more here.
Keywords: vinyl acetate; crystalline iodine; spectroscopy; iodine complexes ... See more keywords
Ligand exchange among iodine(I) complexes.
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DOI: 10.1039/d1dt04309a
Abstract: A detailed investigation of ligand exchange between iodine(I) ions in [N⋯I⋯N]+ halogen-bonded complexes is presented. Ligand exchange reactions were conducted to successfully confirm whether iodine(I) complex formation, via the classical [N⋯Ag⋯N]+ to [N⋯I⋯N]+ cation exchange… read more here.
Keywords: exchange reaction; exchange; iodine complexes; ligand exchange ... See more keywords
Iodine(i) complexes incorporating sterically bulky 2-substituted pyridines
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DOI: 10.1039/d2ra01390h
Abstract: The silver(i) and iodine(i) complexes of the 2-substituted pyridines 2-(diphenylmethyl)pyridine (1) and 2-(1,1-diphenylethyl)pyridine (2), along with their potential protonated side products, were synthesised to investigate the steric limitations of iodine(i) complex formation. The complexes were… read more here.
Keywords: incorporating sterically; iodine complexes; complexes incorporating; substituted pyridines ... See more keywords
Solid-State Preparation and Characterization of 2-Hydroxypropylcyclodextrins-Iodine Complexes as Stable Iodophors
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DOI: 10.3390/biom13030474
Abstract: The use of iodine as antiseptic poses some issues related to its low water solubility and high volatility. Stable solid iodine-containing formulations are highly advisable and currently limited to the povidone-iodine complex. In this study,… read more here.
Keywords: state preparation; solid state; iodine complexes;