Synthesis of Sulfur-Substituted Bicyclo[1.1.1]pentanes by Iodo-Sulfenylation of [1.1.1]Propellane
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DOI: 10.1021/acs.orglett.2c02875
Abstract: Thiols easily react with [1.1.1]propellane to give sulfur-substituted bicyclo[1.1.1]pentanes in radical reactions, but this reactivity is not replicated in the case of heterocyclic thiols. Herein, we address this issue by electrophilically activating [1.1.1]propellane to promote… read more here.
Keywords: bicyclo pentanes; iodo sulfenylation; sulfur substituted; substituted bicyclo ... See more keywords