Iodoaniline Dependent Formation of N‐Aroylguanidines versus 2‐Aminoquinazolinones from Palladium(0) Catalysed Aminocarbonylation of N‐Arylguanidines
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DOI: 10.1002/ejoc.202400803
Abstract: Abstract A family of N,N´‐diaryl‐N″‐(pyridine‐2‐ylmethyl)guanidines (B) were prepared in 70%−92% yields and subjected to palladium(0) catalyzed aminocarbonylation reactions with aryl iodides using CsOH/CHCl3 mixture as CO surrogate to afford the corresponding N‐aroylguanidines (C) in 70%−93%… read more here.
Keywords: dependent formation; formation aroylguanidines; iodoaniline dependent; aroylguanidines versus ... See more keywords