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Published in 2020 at "Dalton transactions"
DOI: 10.1039/c9dt04818a
Abstract: Two iodobismuthate-based organic-inorganic hybrids, [M(DMSO)8][Bi2I9] (M = La (1), Bi (2)), have been successfully designed and synthesized by using solvated metal cations as structure-directing agents (SDAs). 1 displays transient high-temperature thermochromism, which is similar to…
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Keywords:
iodobismuthate;
thermo;
iodobismuthate hybrids;
solvated metal ... See more keywords
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Published in 2023 at "Dalton transactions"
DOI: 10.1039/d3dt00490b
Abstract: New iodobismuthate hybrids with lanthanide complex counter cations, [Ln(DMF)8][Bi2I9] (Ln = La (1), Eu (2)) and [Tb(DMF)8]2[Bi2I9]2 (3) (DMF = N,N-dimethylformamide), were prepared using solvated Ln(III) complexes formed in situ as structure-directing agents. The dimeric…
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Keywords:
iodobismuthate hybrids;
structures photoelectric;
syntheses structures;
hybrids lanthanide ... See more keywords