New discrete iodometallates with in situ generated triimidazole derivatives as countercations (Mn+ = Ag+, Pb2+, Bi3+)
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DOI: 10.1039/c6ra27510a
Abstract: Through employing the solvothermal in situ N-alkylation of organic bases with alcohol molecules, four new iodometallates [L1]2[Ag8I12]I2 (L13+ = 1,1′,1′′-(benzene-1,3,5)tris(3-methyl-1H-imidazol-3-ium)) 1, [L1]2[Ag6I12] 2, [L1]2[Pb3I12]·2H2O 3, and [L1][Bi2I9] 4 were obtained. L13+ originates from the in… read more here.
Keywords: iodometallates situ; situ generated; anionic cluster; discrete iodometallates ... See more keywords