Articles with "iodonio rearrangement" as a keyword



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Oxidative Fluoroarylation of Benzylidenecyclopropanes with HF·Py and Aryl Iodides via Iodonio-[3,3]-Rearrangement.

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Published in 2022 at "Organic letters"

DOI: 10.1021/acs.orglett.2c01150

Abstract: Reported herein is an in situ-generated hypervalent iodine-incorporating fluoroarylation of benzylidenecyclopropanes using commercially available HF·Py and aryl iodides as fluorine and aryl sources, respectively. The reaction proceeds via regioselective 1,2-fluoroiodination of a double bond followed… read more here.

Keywords: aryl iodides; fluoroarylation benzylidenecyclopropanes; iodonio rearrangement; benzylidenecyclopropanes aryl ... See more keywords