New kinetic and mechanistic aspects of photosensitization of iodonium salts in photopolymerization of acrylates
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DOI: 10.1039/c7ra05978g
Abstract: 1,3-Bis(p-bromophenylamino)squaraine which functions as an electron-transfer photosensitizer for a wide range of diphenyliodonium salts radical photoinitiators of triacrylate polymerization under UV-blue light irradiation is presented. The functionality of the photosensitizer is determined by the presence… read more here.
Keywords: radical polymerization; kinetic mechanistic; iodonium salts; iodonium ... See more keywords
Two-step continuous-flow synthesis of 6-membered cyclic iodonium salts via anodic oxidation
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DOI: 10.3762/bjoc.19.2
Abstract: We describe a multi-step continuous-flow procedure for the generation of six-membered diaryliodonium salts. The accompanying scalability and atom economy are significant improvements to existing batch methods. Benzyl acetates are submitted to this two-step procedure as… read more here.
Keywords: cyclic iodonium; two step; step; continuous flow ... See more keywords