Regioselective Functionalization of the [ closo-1-CB9H10]- Anion through Iodonium Zwitterions.
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DOI: 10.1021/acs.inorgchem.8b01701
Abstract: Reactions of [ closo-1-CB9H9-1-R]- (2, R = H, COOH, C5H11) with PhI(OAc)2 lead to mixtures of regioisomers [ closo-1-CB9H8-1-R-6-IPh] (5[6]) and [ closo-1-CB9H8-1-R-10-IPh] (5[10]) in ratios of ∼3:1 to 1:1, of which the former isomer… read more here.
Keywords: closo cb9h9; cb9h10 anion; closo cb9h10; closo ... See more keywords