Promoting oxo functionalization in the uranyl ion by ligation to ketimides
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DOI: 10.1016/j.jorganchem.2017.08.007
Abstract: Abstract Reaction of [UO2Cl2(THF)2]2 with 8 equiv of Li(N=CtBuPh) or 6 equiv of Li(N=CtBu2) affords the uranyl ketimide complexes, [Li(THF)(Et2O)]2[UO2(N=CtBuPh)4] (1) and [Li(THF)(TMEDA)][UO2(N=CtBu2)3] (2), respectively. Complexes 1 and 2 have been fully characterized, including analysis… read more here.
Keywords: oxo functionalization; functionalization uranyl; ion ligation; ligation ketimides ... See more keywords