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Published in 2017 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.7b02010
Abstract: Bulky and strong electron-donating dibutylamino groups were incorporated onto the peripheral positions of one of the two phthalocyanine ligands in the bis(phthalocyaninato) terbium complex, resulting in the isolation of heteroleptic double-decker (Pc)Tb{Pc[N(C4H9)2]8} {Pc = phthalocyaninate;…
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Keywords:
single ion;
bis phthalocyaninato;
phthalocyaninato terbium;
magnetic performance ... See more keywords
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Published in 2018 at "Chemical Science"
DOI: 10.1039/c8sc01626g
Abstract: A single-ion magnet (Dsp)Er(COT) was obtained by replacing a carbon atom of [Cp*]– in (Cp*)Er(COT) by a soft P atom. Both relaxation barrier and blocking temperature are improved.
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Keywords:
atom;
soft phosphorus;
single ion;
ion magnet ... See more keywords
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Published in 2020 at "Chemical communications"
DOI: 10.1039/c9cc07292f
Abstract: A new air-stable sulfur-ligated Dy(iii) single-ion magnet has been successfully isolated with Ueff = 638 K and hysteresis loops open up to 7 K. In silico studies show that the S co-ligands significantly boost the…
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Keywords:
axiality;
iii single;
single ion;
ion magnet ... See more keywords
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Published in 2020 at "CrystEngComm"
DOI: 10.1039/d0ce00935k
Abstract: A β-diketonate mononuclear dysprosium compound, [Dy(DBM)2(bpy)(CH3OH)2]·Cl− (1) (DBM = dibenzoylmethane, bpy = 2,2′-bipyridine), has been prepared and structurally and magnetically characterized. The metal centers in 1 adopt an approximately square-antiprismatic (SAP) coordination environment with D4d…
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Keywords:
coordination;
single ion;
microenvironment perturbed;
coordination microenvironment ... See more keywords
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Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt03046b
Abstract: A molecular dysprosium(III) complex [Dy(DClQ)3(H2O)2] (1) was used as a building unit for the construction of lanthanide SMMs, leading to the isolation of two dinuclear Dy(III) complexes, namely [Dy2(DClQ)6(MeOH)2] (2) and [Dy2(DClQ)6(bpmo)2]·6MeCN (3) (DClQ =…
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Keywords:
building;
ion magnet;
dy2;
single ion ... See more keywords