A New Bis(phthalocyaninato) Terbium Single-Ion Magnet with an Overall Excellent Magnetic Performance.
Sign Up to like & getrecommendations! Published in 2017 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.7b02010
Abstract: Bulky and strong electron-donating dibutylamino groups were incorporated onto the peripheral positions of one of the two phthalocyanine ligands in the bis(phthalocyaninato) terbium complex, resulting in the isolation of heteroleptic double-decker (Pc)Tb{Pc[N(C4H9)2]8} {Pc = phthalocyaninate;… read more here.
Keywords: single ion; bis phthalocyaninato; phthalocyaninato terbium; magnetic performance ... See more keywords
A soft phosphorus atom to “harden” an erbium(iii) single-ion magnet† †Electronic supplementary information (ESI) available. CCDC 1835954–1835958. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8sc01626g
Sign Up to like & getrecommendations! Published in 2018 at "Chemical Science"
DOI: 10.1039/c8sc01626g
Abstract: A single-ion magnet (Dsp)Er(COT) was obtained by replacing a carbon atom of [Cp*]– in (Cp*)Er(COT) by a soft P atom. Both relaxation barrier and blocking temperature are improved. read more here.
Keywords: atom; soft phosphorus; single ion; ion magnet ... See more keywords
There is nothing wrong with being soft: using sulfur ligands to increase axiality in a Dy(iii) single-ion magnet.
Sign Up to like & getrecommendations! Published in 2020 at "Chemical communications"
DOI: 10.1039/c9cc07292f
Abstract: A new air-stable sulfur-ligated Dy(iii) single-ion magnet has been successfully isolated with Ueff = 638 K and hysteresis loops open up to 7 K. In silico studies show that the S co-ligands significantly boost the… read more here.
Keywords: axiality; iii single; single ion; ion magnet ... See more keywords
Coordination microenvironment perturbed single-ion magnet behavior in a β-diketone Dy(iii) complex
Sign Up to like & getrecommendations! Published in 2020 at "CrystEngComm"
DOI: 10.1039/d0ce00935k
Abstract: A β-diketonate mononuclear dysprosium compound, [Dy(DBM)2(bpy)(CH3OH)2]·Cl− (1) (DBM = dibenzoylmethane, bpy = 2,2′-bipyridine), has been prepared and structurally and magnetically characterized. The metal centers in 1 adopt an approximately square-antiprismatic (SAP) coordination environment with D4d… read more here.
Keywords: coordination; single ion; microenvironment perturbed; coordination microenvironment ... See more keywords
A single-ion magnet building block strategy toward Dy2 single-molecule magnets with enhanced magnetic performance.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt03046b
Abstract: A molecular dysprosium(III) complex [Dy(DClQ)3(H2O)2] (1) was used as a building unit for the construction of lanthanide SMMs, leading to the isolation of two dinuclear Dy(III) complexes, namely [Dy2(DClQ)6(MeOH)2] (2) and [Dy2(DClQ)6(bpmo)2]·6MeCN (3) (DClQ =… read more here.
Keywords: building; ion magnet; dy2; single ion ... See more keywords